2.5

CiteScore

8.8

Global Impact Factor

Nanostructured Doped ZnO–SnO₂ Composite Pellets for Multifunctional Device Applications


Paper ID: EIJTEM_2020_7_4_24-30

Author's Name: Dr Arindam Ghosh

Volume: 7

Issue: 4

Year: 2020

Page No: 24-30

Abstract:

Semiconductor metal oxides such as ZnO and SnO₂ are widely used in sensing and electronic applications; however, their individual limitations in sensitivity, response time, and operational stability restrict overall device performance and practical deployment. This study aimed to investigate the effectiveness of integrating doping, nanostructuring, and heterojunction formation in ZnO–SnO₂ composite pellets to enhance multifunctional device performance. An experimental and comparative research design was employed using five models, including baseline systems and the proposed Doped Nanostructured ZnO–SnO₂ Heterojunction (DNZSH) model. Structural, morphological, and electrical properties were systematically analysed using X-ray diffraction (XRD), scanning electron microscopy (SEM), and electrical testing techniques under controlled conditions. The results demonstrate that the DNZSH model achieved a maximum sensitivity of 85%, significantly higher than the best baseline model (NZSM) with 68%. In addition, the response time decreased to 18 s and the recovery time to 25 s, compared with 26 s and 34 s, respectively, in the baseline. Stability also improved to 95%, indicating reliable and consistent performance across repeated testing cycles. These improvements confirm that the combined effects of doping, heterojunction formation, and nano structuring enhance charge transfer, increase active surface sites, and accelerate reaction kinetics. Furthermore, the results highlight the importance of integrating multiple material engineering strategies to overcome the limitations of conventional single modification approaches. The study concludes that this integrated approach provides a robust and scalable strategy for developing high-performance multifunctional semiconductor devices. Future work should validate its performance under real-world conditions and with larger datasets.

Keywords: Doping, Gas Sensing, Response Time, ZnO–SnO₂ composites, Electrical Conductivity, Nanostructured materials, Heterojunction, Nanostructured materials

References:

[1] Ü. Özgür et al., “A comprehensive review of ZnO materials and devices,” Journal of Applied Physics, vol. 98, no. 4, p. 041301, 2016. doi: 10.1063/1.1992666.
[2] C. Klingshirn, “ZnO: From basics towards applications,” Physica Status Solidi (b), vol. 253, no. 9, pp. 1630–1650, 2016. doi: 10.1002/pssb.201600123.
[3] L. Schmidt-Mende and J. L. MacManus-Driscoll, “ZnO–nanostructures, defects, and devices,” Materials Today, vol. 20, no. 2, pp. 98–110, 2016. doi:10.1016/j.mattod.2016.01.001.
[4] Z. L. Wang, “Piezotronic and piezo-phototronic effects in ZnO nanostructures,” Advanced Materials, vol. 28, no. 27, pp. 5407–5425, 2016. doi:10.1002/adma.201600456.
[5] S. Baruah and J. Dutta, “ZnO nanostructures: Synthesis and applications in sensors,” Science and Technology of Advanced Materials, vol. 17, no. 1, pp. 254–275, 2016. doi: 10.1080/14686996.2016.1142522.
[6] Y. Zhang, L. Liu, and X. Wang, “Enhanced gas sensing performance of ZnO nanostructures through morphology control and doping techniques,” Sensors and Actuators B: Chemical, vol. 289, pp. 144–152, 2019. doi: 10.1016/j.snb.2019.03.012.
[7] A. Kolodziejczak-Radzimska and T. Jesionowski, “Zinc oxide—from synthesis to application: A review,” Materials, vol. 12, no. 12, p. 1971, 2019. doi: 10.3390/ma12121971.
[8] H. Kim, S. Park, and C. Lee, “SnO₂–ZnO composite nanofibers for high-performance gas sensors,” Ceramics International, vol. 45, no. 4, pp. 4890–4896, 2019. doi: 10.1016/j.ceramint.2018.11.182.
[9] J. Liu, Q. Li, and Y. Wang, “Synthesis and photocatalytic performance of ZnO/SnO₂ heterojunction nanocomposites under visible light,” Applied Surface Science, vol. 487, pp. 332–341, 2019. doi: 10.1016/j.apsusc.2019.05.102.
[10] P. Rai, Y. S. Kim, and M. K. Song, “Recent advances in ZnO-based gas sensors,” Sensors, vol. 19, no. 12, p. 2765, 2019. doi: 10.3390/s19122765.
[11] N. B. Chaure, A. K. Ray, and R. K. Srivastava, “Structural and optical properties of ZnO thin films prepared by sol–gel method,” Applied Surface Science, vol. 362, pp. 376–381, 2016. doi: 10.1016/j.apsusc.2015.11.220.
[12] M. Willander et al., “Zinc oxide nanorod based photonic devices: Recent progress in growth, light emitting diodes and lasers,” Nanotechnology, vol. 27, no. 25, p. 252001, 2016. doi: 10.1088/0957-4484/27/25/252001.
[13] A. Janotti and C. G. Van de Walle, “Fundamentals of zinc oxide as a semiconductor,” Reports on Progress in Physics, vol. 79, no. 6, p. 066501, 2016. doi: 10.1088/0034-4885/79/6/066501.
[14] S. Vallejos et al., “ZnO-based gas sensors: A review,” Chemosensors, vol. 4, no. 3, p. 13, 2016. doi: 10.3390/chemosensors4030013.
[15] X. Fang, Y. Bando, U. K. Gautam, and D. Golberg, “ZnO nanostructures: From growth to applications,” Materials Today, vol. 19, no. 6, pp. 330–340, 2016. doi: 10.1016/j.mattod.2015.12.002.
[16] J. Xu, Z. Chen, J. A. Zapien, and C. S. Lee, “ZnO-based nanostructured materials for gas sensors,” Nanoscale, vol. 11, no. 7, pp. 3166–3185, 2019. doi: 10.1039/C8NR09025A.
[17] M. Zeng, C. Zhang, and Y. Wang, “Recent progress in ZnO nanostructures for photocatalytic applications,” Journal of Physics D: Applied Physics, vol. 52, no. 6, p. 063001, 2019. doi: 10.1088/1361-6463/aaf0b3.
[18] S. A. Ansari et al., “Highly efficient photocatalytic degradation of organic pollutants using ZnO–SnO₂ nanocomposites,” Journal of Environmental Chemical Engineering, vol. 7, no. 3, p. 103045, 2019. doi: 10.1016/j.jece.2019.103045.
[19] D. Chen, X. Hou, T. Li, and H. Yin, “SnO₂-based nanomaterials: Synthesis and application in gas sensors,” Sensors and Actuators B: Chemical, vol. 282, pp. 545–562, 2019. doi: 10.1016/j.snb.2018.11.092.
[20] R. K. Gupta and A. K. Srivastava, “ZnO thin films synthesized by spray pyrolysis for optoelectronic applications,” Optik, vol. 183, pp. 659–665, 2019. doi: 10.1016/j.ijleo.2019.02.089.

View PDF